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Q15 (CISF/2024) Science & Technology › Basic Science (Physics, Chemistry, Biology)

Which one among the following elements has the highest catenation property?

Explanation

Catenation is the ability of an element to form long chains or rings by bonding with atoms of the same element. Carbon (B) exhibits the highest catenation property among all known elements. This is due to its small atomic size and the high strength of the C-C covalent bond (bond enthalpy of approximately 348 kJ/mol), which allows it to form stable, extensive structures.

  • Silicon: Shows catenation but to a much lesser extent than carbon because the Si-Si bond is weaker.
  • Nitrogen and Oxygen: Show very limited catenation. In these elements, the presence of lone pairs on small atoms leads to significant inter-electronic repulsion, which weakens the N-N and O-O single bonds compared to the C-C bond.

Carbon's exceptional catenation is the fundamental reason for the existence of the vast number of organic compounds.

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