Question map
Consider the following : 1. Carbon monoxide 2. Methane 3. Ozone 4. Sulphur dioxide Which of the above are released into atmosphere due to the burning of crop/biomass residue?
Explanation
The correct answer is option D (1, 2, 3 and 4).
Biomass burning is a major source of gaseous pollution such as carbon monoxide (CO), methane (CH4), nitrous oxides (NOx) and hydrocarbons in the troposphere[1]. Additionally, greenhouse gas emissions from burning crop residues consist of methane (CH4) and nitrous oxide (N2O) produced by the combustion of crop residues burnt in agricultural fields[2]. Major air pollutants emitted from biomass burning include particulate matters (PM), carbon dioxide (CO2), carbon monoxide (CO), sulfur oxides[3], confirming the release of sulfur dioxide.
Regarding ozone, while it may not be directly emitted during combustion, the burning of biomass releases precursor pollutants like nitrogen oxides and volatile organic compounds that lead to ozone formation in the atmosphere. The question asks about substances "released into atmosphere due to burning," which encompasses both direct emissions and secondary atmospheric products. Therefore, all four pollutants—carbon monoxide, methane, ozone, and sulphur dioxide—are associated with crop/biomass residue burning, making option D the comprehensive and correct answer.
Sources- [2] https://www.fao.org/4/i3671e/i3671e.pdf
- [3] https://pmc.ncbi.nlm.nih.gov/articles/PMC7597142/
PROVENANCE & STUDY PATTERN
Guest previewThis question stems from the perennial 'Stubble Burning' crisis in North India rather than a static textbook chapter. While scientifically loose (Ozone is technically a secondary pollutant), the question tests your ability to correlate the 'toxic cocktail' of news headlines with basic combustion chemistry. It forces you to prioritize the 'presence' of pollutants over the strict mechanism of their release.
This question can be broken into the following sub-statements. Tap a statement sentence to jump into its detailed analysis.
- Statement 1: Is carbon monoxide (CO) emitted into the atmosphere by burning crop or biomass residues?
- Statement 2: Is methane (CH4) emitted into the atmosphere by burning crop or biomass residues?
- Statement 3: Is ozone (O3) emitted into the atmosphere by burning crop or biomass residues?
- Statement 4: Is sulphur dioxide (SO2) emitted into the atmosphere by burning crop or biomass residues?
- Explicitly lists CO among the major air pollutants produced by biomass burning.
- Directly ties biomass burning to emission of carbon monoxide (CO).
- States biomass burning is a major source of gaseous pollution including carbon monoxide (CO).
- Specifically identifies CO as an emission from biomass burning in the troposphere.
Says burning biomass releases carbon dioxide and treats biomass as a combustion fuel source, establishing that combustion of biomass emits gaseous carbon species.
A student could apply the general rule that incomplete combustion of carbonaceous fuels (biomass) produces CO as well as CO2 and then check combustion chemistry or emission factors for crop-residue fires.
Identifies biomass and agricultural fires as sources of smoke/brown carbon, showing that burning crop/biomass residues produces smoke and combustion byproducts.
From 'smoke from agricultural fires' one can infer combustion emissions include gases and particulates; the student could look up typical smoke constituents (including CO) from agricultural burning studies.
Discusses biomass burning (forest fires) as a source of volatile combustion products (formaldehyde, formic acid) and separately lists carbon monoxide and dioxide as combustion-related pollutants.
A student could generalize that biomass fires emit various carbon-containing gases and therefore consider CO among common combustion pollutants to investigate further.
Lists carbon monoxide alongside 'smoke' and other combustion-related pollutants, linking CO conceptually to combustion-related air pollution.
Using the association of CO with smoke and combustion, a student could compare urban/vehicle emission sources with rural biomass-smoke source profiles to see if CO appears in agricultural fire measurements.
Notes that carbon monoxide interacts with greenhouse gases and is present in atmospheric chemistry discussions, implying CO is a relevant combustion-related atmospheric species.
A student could use atmospheric chemistry context to look for observational or inventory data on CO from biomass-burning regions to test whether crop-residue burning emits CO.
- Explicitly states that burning crop residues produces methane (CH4) and nitrous oxide (N2O).
- Specifically links CH4 emissions to the combustion of crop residues in agricultural fields.
- Reiterates that emissions from burning crop residues consist of CH4 and N2O gases produced by combustion.
- Notes these emissions come from crop residues burned on-site, directly tying burning to CH4 release.
States that burning biomass releases greenhouse gas (CO2) and treats biomass burning as a combustion process producing gaseous emissions.
A student could combine this with basic combustion chemistry (complete vs incomplete combustion) or emission-factor tables to check whether incomplete combustion of crop residues can produce CH4.
Identifies biomass burning and agricultural fires as major sources of smoke and brown carbon (incomplete combustion products).
One could infer that if biomass burning yields incomplete-combustion products (brown carbon, smoke), it may also emit reduced hydrocarbons like CH4 and then look up measurements from agricultural fire studies.
Explicitly lists organic species (formaldehyde, formic acid) emitted by biomass burning, indicating that a range of volatile organic compounds result from such burning.
Knowing that biomass fires emit volatile organics, a student can reasonably test whether methane is among typical volatile emissions by consulting emission inventories for biomass fires.
Provides a concise list of common methane sources (wetlands, natural gas leakage, livestock) but does not list biomass burning among those examples.
The omission suggests checking specialized emission/source lists or measurement studies to see if biomass burning is commonly counted as a CH4 source or if it is negligible compared with listed sources.
Describes methane's importance as a potent, relatively short-lived GHG, motivating why identifying all CH4 sources (including possible biomass burning) matters for climate impact assessments.
A student could use this as rationale to consult GWP-weighted emission inventories and trace whether agricultural/biomass-fire CH4 contributions are included and how large they are.
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- Explicitly describes emissions from burning crop residues as CH4 and N2O produced by combustion.
- By specifying the gases emitted (CH4 and N2O) for crop-residue burning, it does not list ozone (O3) as a direct emission.
- States greenhouse gas emissions from burning crop residues consist of methane (CH4) and nitrous oxide (N2O).
- Reinforces that the reported direct emissions from crop-residue burning are CH4 and N2O, with no mention of ozone.
- Describes particulate matter (PM) components — black carbon and organic carbon — as being directly emitted from combustion sources.
- Shows typical combustion emissions include PM and carbonaceous species rather than listing ozone as a direct combustion emission.
States that ground‑level ozone forms in smog by the action of sunlight on oxides of nitrogen (NOx) and organic compounds.
A student could check whether biomass burning emits NOx and reactive organic gases; if so, those emissions + sunlight could produce ozone rather than ozone being directly emitted.
Says ground‑level ozone is a pollutant produced in relation to vehicle/industry emissions and cites nitrogen oxides (NOx) from burning fuels as a cause.
Compare the combustion chemistry of crop/biomass burning to fuel combustion to see if similar NOx and organics are produced that can generate ozone photochemically.
Notes that biomass burning (e.g., forest fires) emits volatile organic compounds such as formaldehyde and formic acid into the atmosphere.
Use the fact that organic compounds are ozone precursors: if crop/biomass burning emits these VOCs, they could react (with NOx and sunlight) to form ozone locally.
Explains that burning biomass releases combustion products similar to fossil fuels (e.g., CO2), implying combustion processes emit various gases.
Infer that because biomass combustion is a combustion process, it may also emit NOx and VOCs—check emission studies to see if those precursors are present to enable ozone formation.
Describes that changes in concentrations of reactive species affect both production and destruction of ozone and related oxidants in the troposphere.
A student could infer that adding combustion-derived reactive gases from biomass burning could shift local chemistry toward net ozone production under sunlight.
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- Directly addresses burning of crop residues and lists which gases are emitted from that activity.
- Specifies emissions from burning crop residues consist of CH4 and N2O, not SO2, implying SO2 is not reported for that source in this dataset.
- Identifies sulphur dioxide as an air pollutant associated with industrial and agricultural activities generally.
- Does not, however, link sulphur dioxide specifically to burning crop or biomass residues.
Shows sulphur in the environment is cycled through living matter and that atmospheric H2S can oxidize into SO2.
A student could infer that if plants/biomass contain sulphur, combustion or oxidation of that biomass could produce SO2.
States sulphur compounds such as H2S and SO2 may be derived from natural sources as well as industrial pollution.
Use the idea that natural/biological sources can yield SO2 to consider biomass burning as a plausible natural/anthropogenic source.
Lists biomass/forest burning among anthropogenic sources of atmospheric compounds (in context of acids and oxidation products emitted by combustion).
Combine this with knowledge that combustion oxidizes sulphur to SO2 to test whether biomass firing emits SO2.
Describes biomass as carbonaceous waste burned for energy, noting burning biomass releases combustion products similar to fossil fuels.
By analogy to fossil fuels (which release SO2 when containing sulphur), a student could check sulphur content of crop residues to judge SO2 emissions.
Identifies biomass burning and agricultural fires as significant sources of atmospheric smoke and carbonaceous pollutants.
Use this pattern (biomass burning emits gaseous/particulate pollutants) to investigate whether SO2 is among those emitted from agricultural residue fires.
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- [THE VERDICT]: Trap/Forced Choice. Standard books (Shankar/NCERT) classify Ozone as secondary, but the options force you to select it. This is an 'Applied Science' question.
- [THE CONCEPTUAL TRIGGER]: Air Pollution > Stubble Burning (Winter Pollution). The specific mix of gases mentioned mirrors the 'Delhi Smog' analysis found in The Hindu/Indian Express explainers.
- [THE HORIZONTAL EXPANSION]: Memorize the 8 pollutants in the National Air Quality Index (AQI): PM10, PM2.5, NO2, SO2, CO, O3, NH3, Pb. Contrast this with the 12 pollutants under NAAQS. Study 'Short-Lived Climate Pollutants' (SLCPs): Black Carbon, Methane, Tropospheric Ozone, HFCs.
- [THE STRATEGIC METACOGNITION]: Do not be a rigid scientist. If you know for a fact that Biomass (Organic matter) contains Carbon, Hydrogen, and Sulphur, then CO (1), Methane (2), and SO2 (4) are inevitable. Since no option exists for '1, 2, and 4 only', you must accept the superset [D].
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Biomass burning is a major source of brown carbon and produces soot-like particulates that affect atmospheric radiative properties.
High-yield for questions on air pollution and climate forcing; links agricultural/forest fires to particulate emissions, health impacts, and short-term climate effects, enabling answers on mitigation and policy trade-offs.
- Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 17: Climate Change > Possible Sources of Brown Carbon are > p. 258
- Environment and Ecology, Majid Hussain (Access publishing 3rd ed.) > Chapter 7: Climate Change > 4. Black carbon and climate change > p. 14
Carbon dioxide is the primary atmospheric carbon form in the carbon cycle, while carbon monoxide interacts with greenhouse gases and alters atmospheric chemistry.
Essential for distinguishing greenhouse-gas focus (CO2) from reactive trace gases (CO) in climate and air-quality questions; connects carbon cycle concepts to emissions accounting and atmospheric reaction pathways.
- Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 2: Functions of an Ecosystem > L) The Carbon Cycle > p. 19
- FUNDAMENTALS OF PHYSICAL GEOGRAPHY, Geography Class XI (NCERT 2025 ed.) > Chapter 11: World Climate and Climate Change > Greenhouse Gases(GHGs) > p. 96
- Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 17: Climate Change > 12.3.2 Carbon Dioxide > p. 255
Burning biomass releases roughly similar amounts of carbon dioxide as burning fossil fuels.
Important for debates on bioenergy, carbon neutrality and lifecycle emissions; helps answer questions comparing renewable energy options, emission inventories, and policy implications for biomass use.
- Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 22: Renewable Energy > 22.6 BIOMASS > p. 292
Methane has both natural origins (e.g., wetlands) and human origins (e.g., livestock, fossil fuel leakage).
High-yield for climate-change questions that ask to attribute greenhouse-gas emissions by source. Mastering this helps answer policy and mitigation questions linking agriculture, energy, and emissions inventories.
- Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 17: Climate Change > 17,3.3. Methane > p. 256
- Environment and Ecology, Majid Hussain (Access publishing 3rd ed.) > Chapter 7: Climate Change > 2. greenhouse gases > p. 11
- FUNDAMENTALS OF PHYSICAL GEOGRAPHY, Geography Class XI (NCERT 2025 ed.) > Chapter 11: World Climate and Climate Change > Greenhouse Gases(GHGs) > p. 96
Burning biomass or agricultural residues emits carbonaceous pollutants and gases such as CO2, brown carbon, formaldehyde and formic acid.
Crucial for questions on air pollution, rural practices, and mitigation trade-offs; links agriculture, renewable energy (biomass), and atmospheric chemistry topics frequently tested in environment sections.
- Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 22: Renewable Energy > 22.6 BIOMASS > p. 292
- Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 5: Environmental Pollution > a) Sulphur > p. 102
- Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 17: Climate Change > Possible Sources of Brown Carbon are > p. 258
Different greenhouse gases have different GWPs and lifetimes; methane has a substantially higher short-term GWP and a shorter atmospheric lifetime.
Essential for evaluating the climate impact of specific gases, designing mitigation priorities, and answering comparative questions on gas-specific policy measures and timelines.
- Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 17: Climate Change > CWP & Lifetime of Sreen House Grses: > p. 260
- FUNDAMENTALS OF PHYSICAL GEOGRAPHY, Geography Class XI (NCERT 2025 ed.) > Chapter 11: World Climate and Climate Change > Greenhouse Gases(GHGs) > p. 96
Ground‑level ozone is produced by sunlight-driven reactions of nitrogen oxides and organic compounds, not emitted as O3 directly from combustion.
High-yield for UPSC: distinguishes direct pollutant emissions from secondary pollutant formation, links air‑quality questions (smog, health impacts) with source control (NOx/VOC reduction). Enables answering questions on why controlling precursors matters and on differences between primary and secondary pollutants.
- Environment and Ecology, Majid Hussain (Access publishing 3rd ed.) > Chapter 6: Environmental Degradation and Management > ozone depletion > p. 11
- Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 5: Environmental Pollution > Ozone. > p. 64
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Peroxyacetyl Nitrate (PAN). It is the 'sibling' of Ozone in Photochemical Smog. It causes the characteristic eye irritation during smog events. If UPSC asks about secondary pollutants from burning again, PAN is the next logical target.
The 'Elemental Audit' Hack. Biomass is organic matter = Carbon + Hydrogen + Sulphur + Nitrogen. Burning it implies oxidation. C becomes CO/CO2 (Statement 1). H becomes Hydrocarbons/Methane (Statement 2). S becomes SO2 (Statement 4). Since 1, 2, and 4 are chemically guaranteed and no option matches '1, 2, 4', the only valid choice is [D].
Link this to GS3 (Agriculture & Economy): The 'Stubble Burning' issue is a failure of the 'Market for Crop Residue'. Connect it to solutions like 'Torrefaction' (converting stubble to coal-like pellets) and the 'Pusa Bio-Decomposer'.
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