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The question asks for the option where the pairing of a place with a country is incorrect.
Option 1, Baikonour : Russia, is incorrect. Baikonour is associated with Kazakhstan, not Russia. It is known for being the world`s first and largest operational space launch facility.
Option 2, Kourou : French Guiana, is correct. Kourou is a commune in French Guiana, an overseas region and department of France located in South America.
Option 3, Borobudur : Indonesia is correct. Borobudur is the world`s largest Buddhist temple and a UNESCO World Heritage site located in Magelang, Central Java, Indonesia.
Option 4, Cannes : France is also correct. Cannes is a city located on the French Riviera in France. It is famous for its annual international film festival.
Thus, the answer matches with the correct answer given, which is option 1.