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The correct answer is option 3 - Chlorobenzene.
When benzene reacts with chlorine in the presence of an iron catalyst, it undergoes a substitution reaction called electrophilic aromatic substitution. In this reaction, one of the hydrogen atoms in benzene is replaced by a chlorine atom, resulting in the formation of chlorobenzene.
Option 1 - Benzene hexachloride is incorrect because hexachloride indicates six chlorine atoms attached to the benzene ring, which is not the product formed in this reaction.
Option 2 - Benzyl chloride is incorrect because in this compound, a chlorine atom is attached to a benzyl (CH2Ph) group, where Ph represents a phenyl group. This is a different compound than chlorobenzene.
Option 4 - Benzoyl chloride is incorrect because in this compound, a chlorine atom is attached to a benzoyl group (C6H5CO) which is also different from chlorobenzene.
Therefore, the correct answer is option 3 - Chlorobenzene.