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Consider the following statements: 1. Concentrated H2SO4 is used as a dehydrating agent in esterification reaction. 2. The hydrophilic part of soap is oil and it dissolves in water. 3. Nickel is used as a catalyst in converting vegetable oil into fat. Which of the statements given above are correct?
Explanation
Statement 1 is correct: During esterification (reaction between an alcohol and a carboxylic acid), concentrated H2SO4 acts as both a catalyst and a dehydrating agent. It removes the water produced, which helps shift the chemical equilibrium to favor the formation of the ester.
Statement 2 is incorrect: Soap molecules are amphiphilic. The hydrophilic (water-loving) part is the ionic head, which interacts with water. The hydrophobic (water-fearing) part is the long hydrocarbon chain, which interacts with oil and grease. The statement incorrectly claims the hydrophilic part is oil.
Statement 3 is correct: Hydrogenation is the process used to convert liquid vegetable oils (unsaturated fats) into solid fats (saturated fats like vanaspati ghee). This reaction involves adding hydrogen in the presence of a catalyst, most commonly Nickel (Ni).