The correct answer is option 3: India.
Option 1: USA - While the USA has successfully landed multiple rovers on Mars, such as the Curiosity rover, they have not inserted a spacecraft into Mars` orbit on their maiden attempt. So, this option is incorrect.
Option 2: USA and Russia - Russia has also successfully landed rovers on Mars, but they have not achieved orbit insertion on their maiden attempt either. Therefore, this option is also incorrect.
Option 4: China - China has made significant advancements in space exploration, but they have not yet successfully inserted a spacecraft into Mars` orbit on their maiden attempt. Hence, this option is incorrect.
India, on the other hand, achieved a major milestone by successfully inserting its spacecraft, called the Mars Orbiter Mission (MOM) or Mangalyaan, into Mars` orbit on its maiden attempt in 2014. This made India the first country in the world to accomplish this feat in its first try. Thus, option 3 is the correct answer.
Alert - correct answer should be: None (This means that all the options provided in the question are incorrect, and the correct answer is not given among the options.)