Question map
Consider the following statements : Statement-I : Rainfall is one of the reasons for weathering of rocks. Statement-II : Rain water contains carbon dioxide in solution. Statement-III : Rain water contains atmospheric oxygen. Which one of the following is correct in respect of the above statements ?
Explanation
The correct answer is option A because both Statement-II and Statement-III are factually correct and both explain how rainfall causes weathering of rocks.
Rainfall is naturally acidic with a pH of ~5.6 as CO2 dissolves in the rainwater producing weak carbonic acid[1]. Rain-water contains enough carbon dioxide to make it a weak acid, and solution is the most potent weathering process in limestone regions because the rain-water attacks and dissolves the calcium carbonate[2]. This confirms Statement-II is correct and explains Statement-I.
Chemical weathering processes including solution, carbonation, hydration, oxidation and reduction act on rocks, and water and air (oxygen and carbon dioxide) along with heat must be present to speed up all chemical reactions[3]. Oxidation is the reaction of oxygen in air or water with minerals in the rock, for example, iron in rocks when in contact with air is changed to iron oxide[4]. This confirms Statement-III is correct and also explains Statement-I.
Since both statements are correct and both independently explain how rainfall causes weathering (through carbonation and oxidation respectively), option A is the correct answer.
Sources- [1] Physical Geography by PMF IAS, Manjunath Thamminidi, PMF IAS (1st ed.) > Chapter 6: Geomorphic Movements > Anthropogenic Solution Weathering > p. 91
- [2] Certificate Physical and Human Geography , GC Leong (Oxford University press 3rd ed.) > Chapter 4: Weathering, Mass Movement and Groundwater > CHEMICAL WEATHERING > p. 36
- [3] FUNDAMENTALS OF PHYSICAL GEOGRAPHY, Geography Class XI (NCERT 2025 ed.) > Chapter 5: Geomorphic Processes > Chemical Weathering Processes > p. 40
- [4] Certificate Physical and Human Geography , GC Leong (Oxford University press 3rd ed.) > Chapter 4: Weathering, Mass Movement and Groundwater > CHEMICAL WEATHERING > p. 37
PROVENANCE & STUDY PATTERN
Full viewA classic 'Sitter' derived straight from the fundamentals of Chemical Weathering. It rewards aspirants who didn't just memorize landforms but understood the chemical equations (Oxidation and Carbonation) behind them. If you read NCERT Class XI Geomorphic Processes or GC Leong Ch 4, this was unmissable.
This question can be broken into the following sub-statements. Tap a statement sentence to jump into its detailed analysis.
- Statement 1: Is rainfall a cause of the weathering of rocks?
- Statement 2: Does rainwater contain dissolved carbon dioxide (CO2) from the atmosphere?
- Statement 3: Does dissolved carbon dioxide in rainwater form carbonic acid that chemically weathers rocks?
- Statement 4: Does rainwater contain dissolved atmospheric oxygen (O2)?
- Statement 5: Does dissolved atmospheric oxygen in rainwater contribute to the weathering of rocks through oxidation?
- States that soil absorbs rain-water and keeps underlying rock moist, enhancing chemical weathering
- Notes rain-water picks up organic acids in soil and becomes a stronger agent of rock decomposition
- Identifies water pressures from wetting and drying cycles as a force that fractures rock
- Links repeated moisture-driven expansion/contraction to physical weathering and rock fatigue
- Describes exposure to water or moist air producing chemical changes (e.g., iron oxide) in rock
- Classifies those physical and chemical changes caused by water exposure collectively as weathering
- Explicitly states that as rain falls it dissolves small amounts of atmospheric CO2, forming a weak acid (carbonic acid).
- Directly links dissolved CO2 in rainwater to carbonation (solution weathering) of minerals like limestone, showing functional presence.
- States rainfall is naturally acidic (pH ~5.6) and attributes this acidity to CO2 dissolving in rainwater to produce weak carbonic acid.
- Provides a quantitative pH context that supports the chemical effect of dissolved atmospheric CO2 in rain.
- Notes many minerals are dissolved by water particularly when rainwater contains enough CO2 to make it a weak acid, linking CO2 presence to solution weathering.
- Reinforces that dissolved atmospheric CO2 in rain enhances the solvent power of rainwater for carbonate rocks.
- Defines carbonation as reactions of CO2 producing carbonates, bicarbonates and carbonic acid.
- Explicitly states rainwater dissolves atmospheric CO2 to form a weak acid that can dissolve minerals such as limestone (solution weathering).
- Links this process to dissolution features (e.g., cave/karst formation), showing geological effect.
- States carbonic acid is formed as rain picks up CO2 and additional CO2 from soil, creating a weak carbonic solution.
- Directly asserts this weak carbonic acid dissolves calcium carbonate (limestone), producing karstic features.
- Gives the chemical reaction converting CaCO3 + CO2 + H2O into soluble calcium bicarbonate, demonstrating the dissolution mechanism.
- Summarises that metal carbonates/hydrogencarbonates react with acids to yield soluble products, CO2 and water.
- Explicitly asserts that many gases, including oxygen, dissolve in water.
- Specifies oxygen dissolves to a small extent, implying its presence in aqueous phases.
- Connects dissolved oxygen to sustaining aquatic life, showing functional relevance of dissolved O2.
- States that CO2 dissolves in rainwater to form weak carbonic acid, demonstrating that rainwater dissolves atmospheric gases.
- Provides a direct example of gas uptake by rainwater, supporting the general principle that O2 from the atmosphere can dissolve into rain.
- Describes atmospheric SO2 being carried back to earth after dissolving in rainwater as weak sulphuric acid.
- Offers an additional instance of atmospheric gases dissolving in rainwater, reinforcing that rainwater can contain dissolved gases including O2.
- Explicitly defines oxidation as reaction of oxygen in air or water with rock minerals
- Gives iron → iron oxide (rust) example showing oxygen in water/air causes mineral breakdown
- Links formation of iron oxides to weakening and increased erosion of rocks
- Describes oxidation as combination of a mineral with oxygen to form oxides/hydroxides
- States oxidation occurs where there is ready access to the atmosphere and water (i.e., oxygen + water present)
- Lists oxygen (with surface/soil water) as an agent driving chemical weathering processes
- Notes that presence of water and oxygen speeds up chemical reactions involved in weathering
- [THE VERDICT]: Sitter. Direct hit from NCERT Class XI (Fundamentals of Physical Geography), Chapter 6: Geomorphic Processes and GC Leong Chapter 4.
- [THE CONCEPTUAL TRIGGER]: Chemical Weathering mechanisms. Specifically, identifying the active agents (Water, Oxygen, Carbon Dioxide) and their corresponding processes (Solution, Oxidation, Carbonation).
- [THE HORIZONTAL EXPANSION]: Memorize the 'Big 5' Chemical Weathering types: 1. Solution (Solubility), 2. Carbonation (CO2 + Water = Carbonic Acid vs Limestone), 3. Hydration (Water absorption e.g., Anhydrite to Gypsum), 4. Oxidation (Rusting of Iron), 5. Hydrolysis (H+ ions turning Feldspar to Clay).
- [THE STRATEGIC METACOGNITION]: Don't just read 'Weathering breaks rocks'. Ask 'What is the chemical reaction?'. The question simply converted two basic chemical equations into English sentences: (H2O + CO2 → Carbonic Acid) and (Fe + O2 + H2O → Rust).
Rainwater interacting with soil and rock promotes chemical reactions that decompose minerals.
High-yield for questions on weathering mechanisms and soil formation; links geomorphology with hydrology and pedology. Enables answers explaining why humid regions have faster chemical breakdown and soil development.
- Certificate Physical and Human Geography , GC Leong (Oxford University press 3rd ed.) > Chapter 4: Weathering, Mass Movement and Groundwater > CHEMICAL WEATHERING > p. 36
- Science-Class VII . NCERT(Revised ed 2025) > Chapter 5: Changes Around Us: Physical and Chemical > 5.7.1 Weathering of rocks > p. 67
Repeated wetting and drying produces water pressures and expansion/contraction that fracture rocks.
Useful for distinguishing mechanical vs chemical weathering processes and for explaining episodic rock breakdown (e.g., in monsoon climates). Connects to landslides, rockfalls and mass movement topics frequently tested.
- FUNDAMENTALS OF PHYSICAL GEOGRAPHY, Geography Class XI (NCERT 2025 ed.) > Chapter 5: Geomorphic Processes > Physical Weathering Processes > p. 41
- Physical Geography by PMF IAS, Manjunath Thamminidi, PMF IAS (1st ed.) > Chapter 6: Geomorphic Movements > Landslides in India > p. 89
Warm, wet climates accelerate chemical weathering while dry climates favour mechanical weathering.
Core concept for linking climate zones to landscape evolution, erosion patterns and soil profiles; helps answer comparative questions about regional geomorphology and environmental adaptation.
- Certificate Physical and Human Geography , GC Leong (Oxford University press 3rd ed.) > Chapter 4: Weathering, Mass Movement and Groundwater > CHEMICAL WEATHERING > p. 37
- Certificate Physical and Human Geography , GC Leong (Oxford University press 3rd ed.) > Chapter 7: Arid or Desert Landforms > The Mechanics of Arid Erosion > p. 69
Carbonation describes CO2 dissolving in water to form carbonic acid which dissolves carbonate minerals such as limestone.
High-yield for physical geography and geomorphology questions; explains karst and cave formation, links chemical weathering to rock-cycle and landform evolution, and helps answer questions on weathering mechanisms and landscape change.
- Physical Geography by PMF IAS, Manjunath Thamminidi, PMF IAS (1st ed.) > Chapter 6: Geomorphic Movements > Carbonation – Natural Solution Weathering > p. 90
- Certificate Physical and Human Geography , GC Leong (Oxford University press 3rd ed.) > Chapter 4: Weathering, Mass Movement and Groundwater > CHEMICAL WEATHERING > p. 36
Rainwater attains slight acidity because dissolved atmospheric CO2 forms weak carbonic acid, giving a characteristic pH around 5.6.
Important for environmental chemistry and atmospheric studies; distinguishes natural acidity from anthropogenic acid rain and connects to impacts on soils, vegetation, and built structures—useful for questions on pollution vs natural processes.
- Physical Geography by PMF IAS, Manjunath Thamminidi, PMF IAS (1st ed.) > Chapter 6: Geomorphic Movements > Anthropogenic Solution Weathering > p. 91
- Certificate Physical and Human Geography , GC Leong (Oxford University press 3rd ed.) > Chapter 4: Weathering, Mass Movement and Groundwater > CHEMICAL WEATHERING > p. 36
Dissolution of atmospheric CO2 in rainwater contributed to removal of CO2 from the atmosphere and to formation/chemistry of early oceans.
Useful for questions on Earth's early atmosphere and ocean formation; links planetary evolution, the carbon cycle, and long-term sequestration processes—helps tackle comparative planetology and geochemical cycle questions.
- FUNDAMENTALS OF PHYSICAL GEOGRAPHY, Geography Class XI (NCERT 2025 ed.) > Chapter 2: The Origin and Evolution of the Earth > Evolution of Atmosphere and Hydrosphere > p. 16
- Physical Geography by PMF IAS, Manjunath Thamminidi, PMF IAS (1st ed.) > Chapter 3: Geological Time Scale The Evolution of The Earths Surface > 3. Geological Time Scale – The Evolution of The Earth's Surface > p. 43
Dissolved CO2 in water produces weak carbonic acid that chemically dissolves carbonate rocks such as limestone.
High-yield for physical geography questions on chemical weathering and landform development (karst, caves). Connects weathering processes to rock types and landscape evolution, useful for explaining formation of solutional landforms and human–environment interactions.
- Physical Geography by PMF IAS, Manjunath Thamminidi, PMF IAS (1st ed.) > Chapter 6: Geomorphic Movements > Carbonation – Natural Solution Weathering > p. 90
- Physical Geography by PMF IAS, Manjunath Thamminidi, PMF IAS (1st ed.) > Chapter 17: Major Landforms and Cycle of Erosion > Chemistry Behind Karst Landforms > p. 227
Hydrolysis of Feldspar. While Carbonation weathers Limestone, Hydrolysis is the primary enemy of Granite (turning Feldspar into Kaolin Clay). Expect a future statement: 'Hydrolysis is the main weathering process in granitic terrains of humid tropics.'
The 'Universal Solvent' Logic. Water in nature is never pure H2O; it interacts with the atmosphere. Since the atmosphere contains CO2 and O2, rain *must* contain them. If rocks rust (oxidation) or dissolve (limestone), these dissolved gases are the only logical culprits. The science is circular and self-evident.
Environment & Climate Change (Enhanced Weathering). The weathering of silicate rocks consumes atmospheric CO2 (The Walker Thermostat). This is a natural carbon sink. In Mains, link this to 'Enhanced Rock Weathering' as a Geo-engineering solution for Carbon Sequestration.