Sure, here is an explanation of the matching of the Organisation with their respective Headquarters:

A. International Atomic Energy Agency - The headquarters of the International Atomic Energy Agency (IAEA) is located in Vienna, Austria. The IAEA is an international organization that promotes the peaceful use of nuclear energy, safeguards against the misuse of nuclear materials, and facilitates cooperation among member states in nuclear technology and applications.

B. International Telecommunication Union - The headquarters of the International Telecommunication Union (ITU) is located in Geneva, Switzerland. The ITU is a specialized agency of the United Nations that is responsible for coordinating international telecommunications standards and regulations.

C. Council of the European Union - The Council of the European Union, also known as the Council of Ministers, does not have a fixed headquarters. Its meetings take place in different cities, primarily in Brussels, Belgium. The Council of the European Union is one of the main decision-making bodies of the European Union and represents the member states` governments.

D. Organisation for Economic Cooperation and Development - The headquarters of the Organisation for Economic Cooperation and Development (OECD) is located in Paris, France. The OECD is an international organization that promotes economic growth, development, and stability among its member countries through policy coordination, research, and analysis.

Therefore, the correct matching is A-4, B-2, C-1, D-3.