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The correct answer is option 1: I, II, and III.
Pectin is a complex carbohydrate that is found in the plant cell wall. It acts as a glue-like substance, helping to hold plant cells together.
Lignin is another component of the plant cell wall. It is a complex polymer that provides rigidity and strength to the cell wall.
Cutin is a waxy substance that is present on the outer layer of plant cells. It acts as a protective barrier, preventing water loss and protecting the cell from pathogens.
Chitin, on the other hand, is not found in the plant cell wall. It is a tough, fibrous substance that is primarily found in the exoskeleton of animals such as insects and crustaceans. Therefore, option 2 (I, II, III, and IV) is incorrect.
To summarize, pectin, lignin, and cutin are substances that occur in the plant cell wall, while chitin does not.