Assertion (A) >: In the periodic table of chemical elements, electron affinity is always found to increase from top to bottom in a group. Reason (R) >: In a group, the atomic radial generally increase from top to bottom.

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Q: 105 (IAS/2003)

Assertion (A): In the periodic table of chemical elements, electron affinity is always found to increase from top to bottom in a group.
Reason (R): In a group, the atomic radial generally increase from top to bottom.

question_subject: 

Science

question_exam: 

IAS

stats: 

0,19,31,19,8,4,19

keywords: 

{'atomic radial': [0, 0, 1, 0], 'electron affinity': [0, 0, 2, 0], 'periodic table': [0, 0, 0, 1], 'chemical elements': [0, 0, 2, 1], 'group': [0, 1, 0, 0]}

The correct answer is option 4, which means that the assertion (A) is false, but the reason (R) is true.

Option 4 asserts that the electron affinity does not always increase from top to bottom in a group in the periodic table. This assertion is accurate as, generally, electron affinity decreases moving down a group (vertical column) on the periodic table. This trend occurs because electrons added to atoms further down a group must go into higher energy levels that are further from the nucleus, therefore, these atoms don`t attract additional electrons as strongly.

On the other hand, the reason (R) is true. In a group, atomic radii generally increase from top to bottom. This is due to an increase in the principal quantum number, i.e., the number of electron shells increases leading to a greater distance between the outermost electrons and the nucleus. This causes the atomic size (or atomic radii) to increase.

Option 4 is the correct answer since assertion (A) is false, and reason (R) is true.

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