The correct answer is option 1: I-C, II-D, III-B, IV-A.

Let`s dissect each option to understand why option 1 is correct and the others are incorrect.

Option 1:

I-C: Koraput is associated with the heavy engineering industry.

II-D: Nangal is associated with the fertilizer industry.

III-B: Vadodara is associated with the petrochemical industry.

IV-A: Ranchi is associated with the aluminium industry.

Option 2:

I-C: Koraput is associated with the heavy engineering industry.

II-B: Nangal is not associated with the petrochemical industry.

III-D: Vadodara is not associated with the aluminium industry.

IV-E: Ranchi is not associated with the zinc smelting industry.

Option 3:

I-E: Koraput is not associated with the zinc smelting industry.

II-D: Nangal is associated with the fertilizer industry.

III-C: Vadodara is not associated with the aluminium industry.

IV-A: Ranchi is associated with the aluminium industry.

Option 4:

I-E: Koraput is not associated with the zinc smelting industry.

II-D: Nangal is associated with the fertilizer industry.

III