Option 1: Syria - Syria is a country in the Middle East that does have direct access to the sea. It has a coastline along the Mediterranean Sea, so this option is not the correct answer.

Option 2: Jordan - Jordan is another Middle Eastern country. While it does not have direct access to the sea, it does have a small coastline along the Gulf of Aqaba, which is an extension of the Red Sea. Therefore, this option is also not the correct answer.

Option 3: Azerbaijan - Azerbaijan is a country located in Eastern Europe and Western Asia. It does not have direct access to the sea, as it is surrounded by other countries. However, it does have access to the Caspian Sea, which is the largest enclosed inland body of water in the world. Therefore, Azerbaijan does have access to a sea/ocean, making this option incorrect.

Option 4: Armenia - Armenia is a landlocked country in the South Caucasus region of Eurasia. It does not have direct access to any sea or ocean. Therefore, it is the correct answer.

In conclusion, the correct answer is option 4, Armenia, as it is the only country listed that does not have direct access to a sea/ocean.