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The chemical used as a fixer/developer in photography is sodium thiosulphate, which is option 3.
Although sodium sulphate (option 1) is a chemical compound that is commonly used in various industries, including as a detergent, it is not the correct chemical used in photography.
Sodium sulphide (option 2) is a different compound that is used in various applications, such as in the leather industry, but it is not used as a fixer/developer in photography.
Sodium sulphite (option 4) is another compound that is used as a preservative and a reducing agent in certain processes, but it is not the chemical used in photography.
Sodium thiosulphate, also known as hypo, is the chemical that is used as a fixer/developer in photography. It is used to remove unexposed silver halide crystals from photographic film or paper, thereby fixing the image.