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Based on the given information, we can deduce the following:
1. There are six books stacked on top of each other.
2. The order of the books from top to bottom is as follows: Physics, Civics, Mathematics, English, History, and Commerce.
3. The History book is just above the Commerce book.
4. The Mathematics book is just above the Civics book and just below the Physics book.
5. The English book is located between the History and Civics books.
To determine the book that is between the Mathematics and English books, we need to identify the book that is directly above Mathematics. From the given information, we know that Civics is directly above Mathematics. Since the English book is located between History and Civics, it means that the Civics book must be between the Mathematics and English books.
Therefore, option 4, Civics, is the book that is between the Mathematics and English books.