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The National Capital Region comprises several districts that surround the capital city. The question is asking us to identify the district that is not part of the National Capital Region. Option 1, Muzaffarnagar, is the correct answer. Muzaffarnagar is a district in the state of Uttar Pradesh, which is not included in the National Capital Region.
Option 2, Bulandshahar, is incorrect because Bulandshahar is a district in Uttar Pradesh and is part of the National Capital Region.
Option 3, Panipat, is incorrect because Panipat is a district in the state of Haryana and is also part of the National Capital Region.
Option 4, Rewari, is incorrect because Rewari is a district in Haryana and is included in the National Capital Region.
Therefore, the correct answer is Option 1, Muzaffarnagar, as it is the only district that is not part of the National Capital Region.