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Out of the given options, the solution that will turn phenolphthalein solution pink is option 2, Solution `B`.
To dissect each option:
Option 1, Solution `A` is plain water. Plain water does not have any acidic or basic properties to cause a color change in phenolphthalein solution. Therefore, it would not turn pink.
Option 2, Solution `B` is a solution of an alkali. Alkalis are substances that have a higher concentration of hydroxide ions (OH-) and can react with phenolphthalein solution to turn it pink.
Option 3, Solution `C` is a solution of an acid. Acids have a higher concentration of hydrogen ions (H+) and cannot react with phenolphthalein solution to turn it pink.
Option 4, Solution `D` is a solution of sodium chloride. Sodium chloride is a neutral substance and does not have any acidic or basic properties to react with phenolphthalein solution. Therefore, it would not turn pink.
In conclusion, option 2, Solution `B`, is the correct answer as it is the only solution containing an alkali that can react with phenolphthalein solution to turn it pink.