In this question, we are asked to identify the option that is NOT correctly matched. Option 1 states that Russia is matched with bauxite. Bauxite is a type of ore from which aluminum is extracted. However, Russia is not known for being a major producer of bauxite. Therefore, option 1 is the correct answer because it is not correctly matched.

Option 2 states that Mexico is matched with silver. This is correct because Mexico is one of the largest producers of silver in the world.

Option 3 states that Bolivia is matched with tin. This is also correct as Bolivia is known for its significant tin reserves.

Option 4 states that the U.S.A. is matched with copper. This is correct as the United States is one of the largest producers of copper globally.

Therefore, the only option that is NOT correctly matched is option 1.