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Q10 (CAPF/2018) Science & Technology › Basic Science (Physics, Chemistry, Biology) › Organic chemistry basics Answer Verified

Which of the following statements about carboxylic acids is/arc correct? 1. Simple aliphatic carboxylic acids are soluble in water. 2. Higher carboxylic acids are practically insoluble in water, 3. The acidity of a carboxylic acid depends on the number of carbon atoms present in the hydrocarbon chain. Select the correct answer using the code given below,

Result
Your answer:  ·  Correct: D
Explanation

The correct answer is Option 4 (1, 2 and 3) because all three statements accurately describe the physical and chemical properties of carboxylic acids.

  • Statement 1: Simple aliphatic carboxylic acids (up to four carbon atoms) are soluble in water. This is due to their ability to form strong intermolecular hydrogen bonds with water molecules.
  • Statement 2: Solubility decreases as the hydrocarbon chain length increases. Higher carboxylic acids are practically insoluble because the hydrophobic nature of the long non-polar alkyl chain outweighs the hydrophilic nature of the carboxyl group.
  • Statement 3: The acidity is influenced by the hydrocarbon chain. Alkyl groups exert an inductive effect (+I effect); as the chain length or branching increases, electron density is pushed toward the carboxyl group, destabilizing the carboxylate ion and slightly weakening the acid compared to formic acid.

Since all statements are scientifically valid, Option 4 is the most comprehensive choice.

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