Question map
Consider the following statements : Statement I : Studies indicate that carbon dioxide emissions from cement industry account for more than 5% of global carbon emissions. Statement II : Silica-bearing clay is mixed with limestone while manufacturing cement. Statement III : Limestone is converted into lime during clinker production for cement manufacturing. Which one of the following is correct in respect of the above statements?
Explanation
The cement industry accounts for approximately 5-8% of global CO2 emissions[2], confirming Statement I is correct.
Statement II is correct: Limestone is the basic raw material for the cement industry[3], and limestone contains small quantities of silica, alumina, iron-oxides, phosphorus and sulphur[4]. Silica-bearing materials including clay are indeed mixed with limestone in cement production.
Statement III is also correct: Decomposition of calcium carbonate to calcium oxide and carbon dioxide on heating is an important decomposition reaction used in various industries. Calcium oxide is called lime or quick lime. It has many uses β one is in the manufacture of cement.[5]
However, only Statement III explains Statement I. The CO2 emitted originates from the use of fossil fuels in the high-temperature calcination step (~40% emissions) and from the chemistry of limestone (CaCO3) breaking down into lime (CaO) and CO2 (~60% emissions)[6]. The conversion of limestone to lime directly releases CO2, explaining the industry's high emissions. Meanwhile, mixing clay with limestone (Statement II) is a manufacturing practice but doesn't directly explain the CO2 emissions.
Sources- [1] https://www.sciencedirect.com/science/article/pii/S2666790823000721
- [2] https://www.weforum.org/stories/2024/09/cement-production-sustainable-concrete-co2-emissions/
- [3] NCERT. (2022). Contemporary India II: Textbook in Geography for Class X (Revised ed.). NCERT. > Chapter 5: Print Culture and the Modern World > Rock Minerals > p. 111
- [4] Geography of India ,Majid Husain, (McGrawHill 9th ed.) > Chapter 7: Resources > Natural Resources of India > p. 24
- [5] Science , class X (NCERT 2025 ed.) > Chapter 1: Chemical Reactions and Equations > Figure 1.4 > p. 8
- [6] https://www.sciencedirect.com/science/article/pii/S2666790823000721
PROVENANCE & STUDY PATTERN
Full viewThis is a classic 'Static-Current Hybrid'. The raw material (Limestone/Clay) and process (Calcination) are pure NCERT Class 10 Science/Geography, while the emission statistic (>5%) is a recurring theme in Climate Change reports (IPCC/IEA). The strategy is to link 'Industrial Processes' directly to their 'Environmental Footprint' rather than studying them in silos.
This question can be broken into the following sub-statements. Tap a statement sentence to jump into its detailed analysis.
- Statement 1: Do studies indicate that CO2 emissions from the global cement industry account for more than 5% of total global carbon (CO2) emissions?
- Statement 2: In cement manufacturing, is silica-bearing clay mixed with limestone as a raw material for producing cement clinker?
- Statement 3: During clinker production in cement manufacturing, is limestone (calcium carbonate) converted into lime (calcium oxide) by calcination?
- Statement 4: Does the calcination reaction that converts limestone to lime during clinker production release CO2 and thereby significantly contribute to the cement industry's carbon emissions?
- Statement 5: Does the practice of mixing silica-bearing clay with limestone in cement manufacture directly generate CO2 emissions that significantly contribute to the cement industry's overall carbon emissions?
- Directly states a numeric share for cement production in global CO2 emissions that is above 5%.
- Provides a range (5β8%) and an absolute value (~2.3 GtCO2/yr), supporting the 'more than 5%' claim.
- States a single-value estimate (8%) for the share of global CO2 emissions from cement manufacturing, which is greater than 5%.
- Specifically attributes the percentage to global cement manufacturing.
Gives an explicit example of a sectoral share (global deforestation β 20% of world's CO2 emissions), illustrating that individual activities/sectors can be expressed as significant percentages of total emissions.
A student could use this sector-share framing and compare published cement-sector CO2 tonnage (from external sources) to global CO2 totals to judge whether cement exceeds 5%.
Provides national and global-emissions percentage context (India's annual emissions β 7% of global emissions), showing that percentages of global emissions are a standard and meaningful way to present contribution.
Use this example of reporting (national % of global) to understand and evaluate claims about a single industry's % share (cement) by comparing industry totals to global totals.
States that CO2 emissions come from a variety of human activities and that human-related emissions have driven atmospheric increases β implying emissions inventories are disaggregated by source.
Recognize that cement is one identifiable human activity in emissions inventories; a student could consult such inventories (sector breakdowns) to see whether cement's share exceeds 5%.
Gives an example of attributing a percentage of a pollutant (black carbon) to particular countries (15β35% from China and India), showing that attributing portions of global pollutants to specific sources/regions is common and feasible.
Use the same approach to attribute CO2: combine known cement-industry emissions by country/region with global CO2 totals to estimate the industry's global percentage.
Notes the significant historical increase in atmospheric CO2 due to human activity, indicating the importance of quantifying sources and their relative contributions over time.
A student could use historical/global CO2 totals as the denominator and compare cement-sector emission time series (numerator) to assess whether the sector's share is above 5%.
- Explicitly lists limestones and shales together as raw materials supplied to the cement industry.
- Refers to a geological stage (Rohtas Stage) composed of limestone and shales that provides raw material for cement β directly linking clayey/shaly material with limestone in supply.
- States limestone is the basic/raw material for the cement industry.
- Establishes limestone as the primary carbonate component in cement manufacture, supporting the limestone half of the proposed mixture.
- Describes limestone composition as containing small quantities of silica and alumina.
- Implies cement raw mixes involve silica/alumina components alongside limestone, supporting the need for silica-bearing materials in clinker production.
- Directly describes thermal decomposition of calcium carbonate to calcium oxide and CO2 on heating.
- Explicitly names calcium oxide as lime/quick lime and links this reaction to manufacture of cement.
- Identifies limestone as composed of calcium carbonate (CaCO3).
- States limestone is used in cement manufacture, connecting the raw material to the industry context.
- Confirms pure limestone is primarily calcium carbonate (calcite).
- Provides mineralogical basis for expecting CaCO3 to undergo thermal decomposition during cement processing.
- Explicitly describes thermal decomposition of calcium carbonate to calcium oxide and carbon dioxide on heating.
- States calcium oxide (lime) is used in the manufacture of cement, linking the reaction to cement production.
- Identifies limestone as the basic raw material for the cement industry.
- Links the raw material (calcium carbonate) directly to cement manufacture, showing where the calcination reaction is applied.
- Defines limestone as calcium carbonate and notes its use in cement manufacture.
- Provides composition context that explains why heating limestone releases CO2 (carbonate content).
- Identifies the primary sources of cement CO2 as fuel use for high-temperature calcination and chemical decomposition of limestone (CaCO3 β CaO + CO2).
- Implies CO2 arises from calcination chemistry and fuel combustion rather than from simply mixing materials.
- States that limestone calcined clay cement (LC3) has substantially lower carbon intensity (40% lower) than Portland cement.
- Explains that calcined clays can be combined with limestone as a blended cement or SCM, indicating the mixing practice reduces rather than adds direct CO2 sources.
- Identifies clinker production as the most carbon-intensive step and highlights that lowering clinker content via blended cements is an effective way to reduce CO2 emissions.
- Supports the idea that substituting clinker with materials like calcined clay + limestone reduces overall emissions, so the mixing practice is a mitigation, not a major direct source.
Gives the chemical rule that heating calcium carbonate (limestone) causes thermal decomposition to calcium oxide and CO2βa direct mineral-origin CO2 source used in cement manufacture.
A student can combine this reaction with the fact that limestone is a main cement feedstock to infer that calcining large amounts of limestone will release CO2 from the rock itself.
States that some industrial processes (explicitly including cement production) emit CO2 via chemical reactions not involving combustion.
One can use this general rule to deduce that CO2 from mineral reactions (like calcination) is a recognized emission source in the cement sector, separate from fuel combustion.
Describes limestone composition as largely calcium carbonate but also containing silica, alumina and other oxidesβthe same components mixed/used in cement raw mix.
A student could link the presence of carbonate in limestone to the decomposition reaction (snippet 9) and note that clay/silica supply non-carbonate components needed for clinker formation, helping separate where CO2 originates.
Provides evidence of the very large scale of limestone production for cement (massive increases in tonnage used as raw material).
Combining the large scale of limestone use with the decomposition rule suggests that mineral-source CO2 from calcining limestone could be large in absolute terms, making it a potentially significant part of industry emissions.
Notes that cement production is listed among the most polluting industries and mentions various pollution forms, implying multiple emission pathways (including chemical/process emissions).
A student can use this contextual point to justify investigating both combustion and chemical-process CO2 in cement manufacture to judge the relative significance of each.
- [THE VERDICT]: Moderate/Sitter. Statements II & III are direct NCERT Class 10 Science (Chemical Reactions). Statement I is a major headline fact in Environment (Cement = ~8% global emissions).
- [THE CONCEPTUAL TRIGGER]: 'Major Industries' (Geography) + 'Greenhouse Gas Sources' (Environment). The intersection is 'Process Emissions'.
- [THE HORIZONTAL EXPANSION]: (1) Cement Additives: Gypsum is added to clinker to *retard* setting time. (2) Waste Utilization: Cement industry uses Fly Ash (from thermal plants) and Slag (from steel plants). (3) Green Cement: LC3 (Limestone Calcined Clay Cement) reduces clinker factor. (4) Steel Sector: Uses Coking Coal (reduction agent), another major CO2 source.
- [THE STRATEGIC METACOGNITION]: Do not just memorize 'Limestone is found in MP'. Apply the 'Input-Process-Output' framework: Input (Limestone+Clay) -> Process (Calcination/Heating) -> Output (Clinker + CO2). If an industry uses Carbonate rocks (CaCO3), it *must* release CO2 as a byproduct.
Individual sectors can contribute large fractions of global CO2 (for example, deforestation accounts for around 20% of global CO2).
High-yield for questions on climate change mitigation and global emission accounting; helps compare sectoral contributions (energy, industry, land-use) and prioritise policy responses. Enables answering comparison and percentage-estimation questions in GS papers and essays.
- Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 24: Climate Change Organizations > Cutting emissions from deforestation - (the Warsaw Framework for REDD+") > p. 330
A country's share of global emissions differs from its per-capita emissions and from sectoral contributions within that country.
Crucial for understanding equity debates in international climate negotiations, evaluating INDCs/NDCs, and interpreting statistics in polity/environment questions. Useful for questions asking to assess responsibilities or to compare countries.
- Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 23: India and Climate Change > 23.1.INDI.6fS POSITION ON CLIMATE CHANGE > p. 299
- Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 23: India and Climate Change > India's Intended Nationally Determined Contribution: At A Glance > p. 309
Different pollutants have different source shares β for example, a large fraction of global black carbon originates from specific countries β so pollutant-type matters when attributing contributions.
Important for distinguishing air-pollution policy from greenhouse-gas policy; helps tackle questions on targeted mitigation measures and health vs climate co-benefits. Enables nuanced answers that separate CO2 sectoral shares from other pollutants.
- Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 17: Climate Change > How far India eontributes to globe? > p. 258
Limestone is the basic carbonate feedstock used in cement manufacture.
High-yield for industrial geography and mineral-resource questions; links to manufacturing location, resource distribution and environmental impact topics. Mastering this helps answer questions on raw-material supply chains, regional industrial maps, and pollution associated with cement plants.
- NCERT. (2022). Contemporary India II: Textbook in Geography for Class X (Revised ed.). NCERT. > Chapter 5: Print Culture and the Modern World > Rock Minerals > p. 111
- Geography of India ,Majid Husain, (McGrawHill 9th ed.) > Chapter 7: Resources > Natural Resources of India > p. 24
Shales (clayey rocks) are cited alongside limestone as materials that supply silica and alumina for cement production.
Useful for questions connecting rock types to industrial inputs and to understand why specific geological formations support cement plants. Enables answering items on rawβmix composition, regional geology-to-industry linkage, and resource suitability.
- Geography of India ,Majid Husain, (McGrawHill 9th ed.) > Chapter 7: Resources > Table 7.14 > p. 25
- Geography of India ,Majid Husain, (McGrawHill 9th ed.) > Chapter 7: Resources > Natural Resources of India > p. 24
Non-carbonate minerals such as gypsum and minor silica/alumina in limestone are noted as part of cement raw materials and use.
Helps tackle questions on the complete composition and processing of cement, regulatory/environmental issues, and allied industries; connects mineralogy, industrial processes and pollution control topics.
- Geography of India ,Majid Husain, (McGrawHill 9th ed.) > Chapter 7: Resources > Natural Resources of India > p. 28
- Geography of India ,Majid Husain, (McGrawHill 9th ed.) > Chapter 7: Resources > Natural Resources of India > p. 24
Calcination converts CaCO3 into CaO and CO2, which is the chemical step producing lime used in cement production.
High-yield for questions on industrial chemistry and cement manufacture; links basic chemical reaction to an industrial process and to environmental issues (CO2 release). Understanding this enables answering questions on raw material transformations and emissions in heavy industries.
- Science , class X (NCERT 2025 ed.) > Chapter 1: Chemical Reactions and Equations > Figure 1.4 > p. 8
The role of Gypsum (CaSO4Β·2H2O). It is the 'Next Logical Question'. While Limestone creates clinker, Gypsum prevents flash-setting. Also, look for 'Fly Ash' usage in Portland Pozzolana Cement (PPC) as a substitute for clinker to lower emissions.
The 'Recipe vs. Reaction' Logic. Statement II describes a *recipe* (mixing clay). Statement III describes a *chemical reaction* (Limestone -> Lime + CO2). Statement I describes *emissions* (CO2). Logically, a chemical reaction that releases gas (III) is the *causal explanation* for emissions, whereas simply mixing ingredients (II) is not. This logic helps isolate that only III explains I.
Mains GS-3 (Environment) & GS-1 (Geography): Cement and Steel are classified as 'Hard-to-Abate' sectors. Unlike power generation (which can switch to solar), cement *cannot* stop emitting CO2 easily because the CO2 comes from the chemistry of the rock itself (Calcination), not just the fuel. This justifies the push for CCUS (Carbon Capture) in industrial policy.