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The correct statement about the refractive index of a material medium with respect to air is option 4: it is always greater than one.
Option 1 is incorrect because the refractive index is always positive. It is a ratio of the speed of light in a vacuum to the speed of light in the medium, and both of these speeds are always positive values.
Option 2 is incorrect because the refractive index represents how much the speed of light is reduced when it passes through the medium compared to a vacuum. If the refractive index were zero, it would mean that the speed of light in the medium is the same as the speed of light in a vacuum, which is not the case in any material medium.
Option 3 is incorrect because the refractive index varies for different materials. It depends on the physical properties of the material, such as its density and composition.
Therefore, the correct answer is option 4: the refractive index of a material medium with respect to air is always greater than one.