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Option 1: Zinc and hydrochloric acid:
When zinc reacts with hydrochloric acid, it produces hydrogen gas. However, this reaction does not turn limewater milky. Therefore, option 1 is not the correct answer.
Option 2: Magnesium carbonate and hydrochloric acid:
When magnesium carbonate reacts with hydrochloric acid, it produces carbon dioxide gas. This gas can turn limewater milky due to the formation of calcium carbonate, which is insoluble and forms a white precipitate. Therefore, option 2 is the correct answer.
Option 3: Methane and oxygen:
When methane reacts with oxygen, it undergoes combustion to produce carbon dioxide and water. This reaction does not produce a gas that can turn limewater milky. Therefore, option 3 is not the correct answer.
Option 4: Copper and dilute hydrochloric acid:
When copper reacts with hydrochloric acid, it produces copper chloride and hydrogen gas. This reaction does not turn limewater milky. Therefore, option 4 is not the correct answer.
In conclusion, the correct answer is option 2, as the reaction between magnesium carbonate and hydrochloric acid produces carbon dioxide gas, which can turn limewater milky.