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The correct answer is option 4: Hydrogen ions do not contain any proton.
Option 1 states that cathode rays are negatively charged particles, which is correct. Cathode rays were later identified as streams of electrons, which are indeed negatively charged particles.
Option 2 states that cathode rays are produced from all gases, which is also correct. When a high voltage is applied to a gas-filled tube, cathode rays can be observed regardless of the gas used.
Option 3 states that electrons are basic constituents of all atoms, which is true. Electrons are subatomic particles that are found orbiting the nucleus of an atom, and they have a negative charge.
However, option 4 states that hydrogen ions do not contain any protons, which is incorrect. Hydrogen ions are formed when a hydrogen atom loses its electron, resulting in a positively charged ion. These hydrogen ions (H+) contain a single proton in their nucleus.
Therefore, option 4 is the incorrect statement among the given options.