Question map
Brominated flame retardants are used in many household products like mattresses and upholstery. Why is there some concern about their use? 1. They are highly resistant to degradation in the environment. 2. They are able to accumulate in humans and animals. Select the correct answer using the code given below.
Explanation
The correct answer is option C (Both 1 and 2).
PBBs (polybrominated biphenyls, a type of brominated flame retardant) are persistent in the environment[1], and biodegradation in water, sediment and soil is not likely to occur easily[1]. This confirms that statement 1 is correctāthese compounds are highly resistant to degradation.
There is evidence of their presence in the environment and in humans[2], which confirms that statement 2 is also correctābrominated flame retardants accumulate in humans and animals. Many of these substances of greatest concern are organic compounds characterised by persistence in the environment, resistance to degradation, and acute and chronic toxicity[3].
Both characteristicsāenvironmental persistence and bioaccumulationāmake brominated flame retardants a matter of significant concern for public health and environmental safety, despite their important role in fire prevention.
Sources- [1] https://one.oecd.org/document/OCDE/GD(94)96/en/pdf
- [2] https://digitallibrary.un.org/record/752652/files/UNEP-POPS-NPOPS-EVAL-RMEs-2005-2008-En.pdf
- [3] https://digitallibrary.un.org/record/487281/files/europe-report.pdf
PROVENANCE & STUDY PATTERN
Full viewThis question masquerades as a specific chemistry query but is actually testing the definition of Persistent Organic Pollutants (POPs). In 2014, BFRs were a hot topic under the Stockholm Convention. If a chemical is a 'global concern', it almost invariably satisfies the PBT criteria: Persistence, Bioaccumulation, and Toxicity.
This question can be broken into the following sub-statements. Tap a statement sentence to jump into its detailed analysis.
- Explicitly states biodegradation in water, sediment and soil is not likely to occur easily for brominated flame retardants.
- Specifically notes certain brominated flame retardant groups (PBBs and PBDPOs) are considered persistent in the environment.
- Describes persistent toxic substances as organic compounds characterised by persistence and resistance to degradation.
- Places such persistent, resistant compounds among the substances of greatest concern, consistent with concern about long environmental lifetimes.
Defines Persistent Organic Pollutants (POPs) as chemicals that 'remain intact for exceptionally long periods' and 'accumulate in fatty tissue', giving a direct pattern for what 'persistent' means for organic, often halogenated, pollutants.
A student could note that many brominated organics are organic chemicals and compare their properties to POPs (e.g., long environmental lifetimes and bioaccumulation) to judge plausibility.
Lists flame retardants as additives in plastics and notes plastics/additives are non-biodegradable and persist in soil, indicating flame retardants can be associated with persistent materials.
One could infer that if flame retardants are embedded in non-biodegradable plastics, they may also persist or be released over long timescales into the environment.
States bioremediation is limited to biodegradable compounds and 'not all compounds are susceptible to rapid and complete degradation', highlighting that some man-made chemicals resist biological breakdown.
A student could apply this general rule to brominated organicsāasking whether they are biodegradable; if not, that supports potential persistence.
Explains pollutants vary in persistence and that some break down by sunlight while others remain for very long times, providing criteria (photolytic, chemical, biological degradability) for assessing persistence.
Using this checklist, a student could check whether brominated flame retardants are susceptible to photolysis, hydrolysis or biodegradation to infer likely persistence.
Describes CFCs as chemically stable with very long atmospheric residence times, giving an example pattern that halogenated compounds can be highly persistent due to chemical stability.
A student could use the analogy that other halogen-containing organics (e.g., brominated compounds) may also be chemically stable and thus persistent, pending specific data.
- States that components of C-PentaBDE are present "in the environment and in humans", indicating accumulation/exposure to people.
- Explicitly links these brominated flame retardant components with regional concern due to their presence and toxicity, implying persistence/exposure pathways.
- Document title and references emphasize "Brominated Flame Retardants: Rising Levels of Concern", indicating environmental and health significance.
- Cites reviews on the significance of brominated flame retardants in the environment, supporting that BFRs are an environmental/health issue related to accumulation/exposure.
- Notes that accidental fires and widespread use can form a source of pollution with brominated flame retardants or their degradation products.
- States Sweden's concern about widespread use and potential harm to man and the environment, implying potential accumulation/exposure to animals and humans.
Defines Persistent Organic Pollutants (POPs) as carbonābased chemicals that remain long in the environment and 'accumulate in the fatty tissue of living organisms' and 'concentrate in living organisms through ... bioaccumulation.'
A student could note that if certain brominated flame retardants are classified or behave like POPs, they would be expected to accumulate in fats and biomagnify up food chains.
Lists 'flame retardants' as additives used in plastics and waste materials, tying flame retardants to persistent consumer products.
Knowing flame retardants are used in longālived plastics, a student could infer potential for environmental release and subsequent exposure of organisms to these brominated additives.
Gives a basic definition of bioaccumulation: increase in pollutant concentration from the environment to the first organism in a food chain.
A student can apply this rule to any persistent, fatāsoluble chemical (such as some flame retardants) to predict uptake by organisms and entry into food chains.
States that certain pesticides (organochlorines) 'accumulate in body fat and blood lipids' and 'persist in the body for many years,' illustrating the pattern for fatāsoluble, persistent chemicals.
By analogy, a student could test whether brominated flame retardants are fatāsoluble and persistent; if so, they may show similar accumulation in animal/human fats.
Mentions several bromineācontaining compounds (halons, hydrobromo fluorocarbons) used in fireārelated applications, linking bromine chemistry to fireāsuppression/retardant uses.
A student could combine this with the POPs/bioaccumulation rules to consider that brominated chemicals used for fire protection might share behaviour (persistence/accumulation) with other brominated compounds.
- [THE VERDICT]: Concept-based Current Affairs. Solvable via the 'POPs Framework' found in Shankar IAS (Chapter 28) or NCERT Biology (Class 12, Ecology).
- [THE CONCEPTUAL TRIGGER]: The Stockholm Convention on Persistent Organic Pollutants. Whenever a new chemical is added (like BFRs were around this time), its properties become high-yield.
- [THE HORIZONTAL EXPANSION]: Memorize the 'Dirty Dozen' POPs (e.g., DDT, PCBs, Dioxins) and the 'Nasty Newcomers' (PFAS, Endosulfan, Diclofenac). Understand the difference: Bioaccumulation (one organism over time) vs. Biomagnification (up the food chain).
- [THE STRATEGIC METACOGNITION]: Do not memorize individual chemical datasheets. Apply the 'Halogen Heuristic': If a man-made organic compound contains Chlorine, Bromine, or Fluorine (Halogens), assume it is lipophilic (fat-loving), persistent, and bioaccumulative until proven otherwise.
The statement asks about resistance to degradation; multiple references discuss how pollutants vary in persistence and whether they are biodegradable or non-biodegradable.
High-yield for UPSC environment questions: understanding persistence underpins topics like pollutant fate, long-range transport, and remediation. It connects to waste management, ecology, and policy questions. Prepare by comparing examples of persistent vs biodegradable pollutants, mechanisms of breakdown (photolysis, microbial degradation), and implications for ecosystem health and cleanup.
- Environment and Ecology, Majid Hussain (Access publishing 3rd ed.) > Chapter 6: Environmental Degradation and Management > Duration of Marine Pollutants > p. 46
- Environment and Ecology, Majid Hussain (Access publishing 3rd ed.) > Chapter 6: Environmental Degradation and Management > Pollutant > p. 33
- Science , class X (NCERT 2025 ed.) > Chapter 13: Our Environment > Activity 13.5 > p. 214
POPs are defined as organic substances that remain intact for long periods, distribute widely, bioaccumulate and are toxic ā directly relevant to claims of chemical persistence.
Frequently tested concept: POPs feature in questions on international conventions, human health, and bioaccumulation. Understanding the defining properties helps evaluate whether a chemical class (e.g., some flame retardants) could be treated as POPs. Study the POPs criteria, examples, and policy responses (e.g., Stockholm Convention).
- Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 28: International Organisation and Conventions > POPs > p. 405
- Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 5: Environmental Pollution > 5.r.r. Classifications > p. 63
References note presence of flame retardants as plastic additives and that bioremediation is limited to biodegradable compounds, highlighting potential remediation challenges for such additives.
Useful for questions on plastic pollution, product composition, and remediation policy. Shows how chemical additives complicate waste management and why persistence of additives matters. Prepare by linking material composition to disposal impacts and remediation feasibility.
- Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 5: Environmental Pollution > 5.12.2. Plastics as a Waste Material in Land Environment > p. 97
- Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 5: Environmental Pollution > Disadvantages of bioremediation > p. 101
Reference [1] defines POPs as organic chemicals that persist, distribute widely and accumulate in fatty tissue of living organisms via bioaccumulation.
High-yield environment topic: explains why certain synthetic organics pose long-term risks to human and wildlife health. Mastering this helps answer questions on pollutant persistence, health impacts, and policy responses. Study by linking POP properties (persistence, lipophilicity, long-range transport) to examples and health effects.
- Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 28: International Organisation and Conventions > POPs > p. 405
Reference [2] describes progressive accumulation of non-degradable chemicals at each trophic level, leading to highest concentrations in top predators including humans.
Core ecology concept often tested in UPSC: connects food chains, human exposure to pollutants, and policy on pesticide residues. Learn typical pathways, implications for food safety, and example chemicals to answer multi-disciplinary questions.
- Science , class X (NCERT 2025 ed.) > Chapter 13: Our Environment > 13.1.1 Food Chains and Webs > p. 212
Reference [3] notes plastics contain additives such as flame retardants, plasticizers and pigments that can be persistent environmental contaminants.
Useful for questions on pollution sources, e-waste and chemical hazards; links manufacturing/materials to environmental and health outcomes. Prepare by mapping common additives, their uses, and environmental/health concerns as case studies.
- Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 5: Environmental Pollution > 5.12.2. Plastics as a Waste Material in Land Environment > p. 97
PFAS (Per- and polyfluoroalkyl substances). Known as 'Forever Chemicals', they are the modern sibling to BFRs. Found in non-stick cookware and water-resistant fabrics. Expect a question on their 'mobility' in water vs. BFRs' tendency to stick to soil/fat.
The 'Definition of Concern' Logic. The question asks why there is 'concern'. In environmental science, 'concern' is defined by persistence and accumulation. If Statement 1 were false (i.e., it degrades easily), there would be no concern. Therefore, for the premise of the question to hold, the statements describing persistence usually must be true.
Link to GS3 Environment (E-Waste Management Rules). BFRs are a primary reason why recycling E-waste is hazardous. Burning plastic wires releases Dioxins/Furans (Mains 2023 theme).