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Q16 (IAS/2014) Environment & Ecology › Pollution & Conservation › Hazardous chemical pollutants Official Key

Brominated flame retardants are used in many household products like mattresses and upholstery. Why is there some concern about their use? 1. They are highly resistant to degradation in the environment. 2. They are able to accumulate in humans and animals. Select the correct answer using the code given below.

Result
Your answer: —  Ā·  Correct: C
Explanation

The correct answer is option C (Both 1 and 2).

PBBs (polybrominated biphenyls, a type of brominated flame retardant) are persistent in the environment[1], and biodegradation in water, sediment and soil is not likely to occur easily[1]. This confirms that statement 1 is correct—these compounds are highly resistant to degradation.

There is evidence of their presence in the environment and in humans[2], which confirms that statement 2 is also correct—brominated flame retardants accumulate in humans and animals. Many of these substances of greatest concern are organic compounds characterised by persistence in the environment, resistance to degradation, and acute and chronic toxicity[3].

Both characteristics—environmental persistence and bioaccumulation—make brominated flame retardants a matter of significant concern for public health and environmental safety, despite their important role in fire prevention.

Sources
  1. [1] https://one.oecd.org/document/OCDE/GD(94)96/en/pdf
  2. [2] https://digitallibrary.un.org/record/752652/files/UNEP-POPS-NPOPS-EVAL-RMEs-2005-2008-En.pdf
  3. [3] https://digitallibrary.un.org/record/487281/files/europe-report.pdf
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Q. Brominated flame retardants are used in many household products like mattresses and upholstery. Why is there some concern about their use…
At a glance
Origin: Mostly Current Affairs Fairness: Low / Borderline fairness Books / CA: 0/10 Ā· 10/10

This question masquerades as a specific chemistry query but is actually testing the definition of Persistent Organic Pollutants (POPs). In 2014, BFRs were a hot topic under the Stockholm Convention. If a chemical is a 'global concern', it almost invariably satisfies the PBT criteria: Persistence, Bioaccumulation, and Toxicity.

How this question is built

This question can be broken into the following sub-statements. Tap a statement sentence to jump into its detailed analysis.

Statement 1
Are brominated flame retardants highly resistant to degradation and therefore persistent in the environment?
Origin: Web / Current Affairs Fairness: CA heavy Web-answerable

Web source
Presence: 5/5
"Biodegradation in water, sediment and soil is not likely to occur easily. It is considered that PBBs and PBDPOs are persistent in the environment,"
Why this source?
  • Explicitly states biodegradation in water, sediment and soil is not likely to occur easily for brominated flame retardants.
  • Specifically notes certain brominated flame retardant groups (PBBs and PBDPOs) are considered persistent in the environment.
Web source
Presence: 4/5
"Many of the substances of greatest concern are organic compounds characterised by persistence in the environment, resistance to degradation, and acute and chronic toxicity."
Why this source?
  • Describes persistent toxic substances as organic compounds characterised by persistence and resistance to degradation.
  • Places such persistent, resistant compounds among the substances of greatest concern, consistent with concern about long environmental lifetimes.

Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 28: International Organisation and Conventions > POPs > p. 405
Strength: 5/5
ā€œSHANKAR Persistent Organic Pollutants (POPs) are organic chemical substances, that is, they are carbon-based. They possess a particular combination of physical and chemical properties such that, once released into the environment, they: • remain intact for exceptionally long periods of time (many years); • become widely distributed throughout the environment as a result of natural processes involving soil, water and, most notably, air, long range environment transport (LRET). • accumulate in the fatty tissue of living organisms including humans, and are found at higher concentrations at higher levels in the food chain; and • are foxic to both humans and wildlife In addition, POPs concentrate in living organisms through another process called bioaccumulation.ā€
Why relevant

Defines Persistent Organic Pollutants (POPs) as chemicals that 'remain intact for exceptionally long periods' and 'accumulate in fatty tissue', giving a direct pattern for what 'persistent' means for organic, often halogenated, pollutants.

How to extend

A student could note that many brominated organics are organic chemicals and compare their properties to POPs (e.g., long environmental lifetimes and bioaccumulation) to judge plausibility.

Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 5: Environmental Pollution > 5.12.2. Plastics as a Waste Material in Land Environment > p. 97
Strength: 4/5
ā€œ5.12.2. Plastics as a Waste Material- in Land Environment Problems with the uncollected plastic waste, include • (i) Choking of drains by plastic carry bags which may lead to unhygienic environment and water borne diseases, • (ii) Causing of illness and possible death of animals that may feed on plastics from garbage bins, • (iii) Non-biodegradable and impervious nature of plastics disposed on soil which may arrest recharge of ground water aquifers, • (iv) presence of additives and plasticizers, fillers, flame retardants and pigments used in the plasticā€
Why relevant

Lists flame retardants as additives in plastics and notes plastics/additives are non-biodegradable and persist in soil, indicating flame retardants can be associated with persistent materials.

How to extend

One could infer that if flame retardants are embedded in non-biodegradable plastics, they may also persist or be released over long timescales into the environment.

Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 5: Environmental Pollution > Disadvantages of bioremediation > p. 101
Strength: 4/5
ā€œā€¢ Bioremediation is limited to those compounds that are biodegradable. Not all compounds are susceptible to rapid and complete degradation. • Biological processes are often highly specific. • It is difficult to extrapolate from bench and pilot_ scale studies to full-scale field operations. • Bioremediation often takes longer time than other treatment process.ā€
Why relevant

States bioremediation is limited to biodegradable compounds and 'not all compounds are susceptible to rapid and complete degradation', highlighting that some man-made chemicals resist biological breakdown.

How to extend

A student could apply this general rule to brominated organics—asking whether they are biodegradable; if not, that supports potential persistence.

Environment and Ecology, Majid Hussain (Access publishing 3rd ed.) > Chapter 6: Environmental Degradation and Management > Duration of Marine Pollutants > p. 46
Strength: 4/5
ā€œPollutants vary in their persistence. On the basis of persistence the pollutants may be classifed in the following categories: • (i) Some reside in environment for thousands of years while others last only a few minutes.• (ii) Some pollutants break down into harmless substances spontaneously or through physical process (like the shattering of large molecules by sunlight).• (iii) Sometimes pollutants are removed from the environment through biological activity. For example, some marine organisms escape permanent damage by metabolising hazardous substances to harmless ones.• (iv) Te volatile components of any oil spill eventually evaporate into the air, leaving the heavier tars behind.ā€
Why relevant

Explains pollutants vary in persistence and that some break down by sunlight while others remain for very long times, providing criteria (photolytic, chemical, biological degradability) for assessing persistence.

How to extend

Using this checklist, a student could check whether brominated flame retardants are susceptible to photolysis, hydrolysis or biodegradation to infer likely persistence.

Environment and Ecology, Majid Hussain (Access publishing 3rd ed.) > Chapter 6: Environmental Degradation and Management > ozone depletion > p. 12
Strength: 3/5
ā€œTe compounds of CFC gases are nontoxic, non-fammable and chemically inert gases. Tese properties make them useful for a wide range of applications including refrigerants, foaming agents, plastic manufacturing, fre extinguishing agents, solvents for freezing food, cleaners for electronic components fne retardant, solvents, aerosol propellants, and the production of foamed plastics. CFCs is widely used because of its properties like non-corrosiveness, non-infammability, low toxicity and chemical stability. CFCs cannot be eliminated from the atmosphere by the usual scavenging processes like photodissociation, oxidation and rain out. Te residence time of CFCs in the atmosphere is estimated to be between 40 to 150 years.ā€
Why relevant

Describes CFCs as chemically stable with very long atmospheric residence times, giving an example pattern that halogenated compounds can be highly persistent due to chemical stability.

How to extend

A student could use the analogy that other halogen-containing organics (e.g., brominated compounds) may also be chemically stable and thus persistent, pending specific data.

Statement 2
Do brominated flame retardants bioaccumulate (accumulate) in humans and animals?
Origin: Web / Current Affairs Fairness: CA heavy Web-answerable

Web source
Presence: 4/5
"in the environment and in humans, and there is evidence of their toxicity. For these reasons the components of C-PentaBDE cause concern in many regions of the world."
Why this source?
  • States that components of C-PentaBDE are present "in the environment and in humans", indicating accumulation/exposure to people.
  • Explicitly links these brominated flame retardant components with regional concern due to their presence and toxicity, implying persistence/exposure pathways.
Web source
Presence: 3/5
"Brominated Flame Retardants: Rising Levels of Concern"
Why this source?
  • Document title and references emphasize "Brominated Flame Retardants: Rising Levels of Concern", indicating environmental and health significance.
  • Cites reviews on the significance of brominated flame retardants in the environment, supporting that BFRs are an environmental/health issue related to accumulation/exposure.
Web source
Presence: 3/5
"Accidental fires in buildings can form a source of pollution with brominated flame retardants or the products of their thermal degradation. 80 Sweden ... The widespread"
Why this source?
  • Notes that accidental fires and widespread use can form a source of pollution with brominated flame retardants or their degradation products.
  • States Sweden's concern about widespread use and potential harm to man and the environment, implying potential accumulation/exposure to animals and humans.

Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 28: International Organisation and Conventions > POPs > p. 405
Strength: 5/5
ā€œSHANKAR Persistent Organic Pollutants (POPs) are organic chemical substances, that is, they are carbon-based. They possess a particular combination of physical and chemical properties such that, once released into the environment, they: • remain intact for exceptionally long periods of time (many years); • become widely distributed throughout the environment as a result of natural processes involving soil, water and, most notably, air, long range environment transport (LRET). • accumulate in the fatty tissue of living organisms including humans, and are found at higher concentrations at higher levels in the food chain; and • are foxic to both humans and wildlife In addition, POPs concentrate in living organisms through another process called bioaccumulation.ā€
Why relevant

Defines Persistent Organic Pollutants (POPs) as carbon‑based chemicals that remain long in the environment and 'accumulate in the fatty tissue of living organisms' and 'concentrate in living organisms through ... bioaccumulation.'

How to extend

A student could note that if certain brominated flame retardants are classified or behave like POPs, they would be expected to accumulate in fats and biomagnify up food chains.

Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 5: Environmental Pollution > 5.12.2. Plastics as a Waste Material in Land Environment > p. 97
Strength: 4/5
ā€œ5.12.2. Plastics as a Waste Material- in Land Environment Problems with the uncollected plastic waste, include • (i) Choking of drains by plastic carry bags which may lead to unhygienic environment and water borne diseases, • (ii) Causing of illness and possible death of animals that may feed on plastics from garbage bins, • (iii) Non-biodegradable and impervious nature of plastics disposed on soil which may arrest recharge of ground water aquifers, • (iv) presence of additives and plasticizers, fillers, flame retardants and pigments used in the plasticā€
Why relevant

Lists 'flame retardants' as additives used in plastics and waste materials, tying flame retardants to persistent consumer products.

How to extend

Knowing flame retardants are used in long‑lived plastics, a student could infer potential for environmental release and subsequent exposure of organisms to these brominated additives.

Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 2: Functions of an Ecosystem > 2.5.t. Bioaccumulation > p. 16
Strength: 5/5
ā€œā€¢ It refers to how pollutants enter a food chain. • In bioaccumulation, there is an increase in concentration of a pollutant from the environment to the first organism in a food chain.ā€
Why relevant

Gives a basic definition of bioaccumulation: increase in pollutant concentration from the environment to the first organism in a food chain.

How to extend

A student can apply this rule to any persistent, fat‑soluble chemical (such as some flame retardants) to predict uptake by organisms and entry into food chains.

Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 29: Environment Issues and Health Effects > Testing Of Pesticide Toxicity > p. 415
Strength: 4/5
ā€œBut never forget that lower LD 50 means higher acute toxicity. • Pesticides once ingested, accumulate in the body fat or pass through. Organochlorine pesticides, for instance, accumulate in body fat and blood lipids. These fat-soluble chemicals persist in the body for many years.ā€
Why relevant

States that certain pesticides (organochlorines) 'accumulate in body fat and blood lipids' and 'persist in the body for many years,' illustrating the pattern for fat‑soluble, persistent chemicals.

How to extend

By analogy, a student could test whether brominated flame retardants are fat‑soluble and persistent; if so, they may show similar accumulation in animal/human fats.

Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 19: Ozone Depletion > Other substances: > p. 269
Strength: 2/5
ā€œBromine containing compounds called halons and HBFCs, i.e. hydrobromo fluorocarbons (both used in fire extinguishers and methyl bromide (a widely used pesticide)). Each bromine atom destroys a hundred times more ozone molecules than what a chlorine atom does. • Bromine + ozone --l: Bromine monoxide --| + chlorine monoxide; Bromine monoxide + Oxygen: Oxygen + Bromine + chlorine • Bromine + ozone --l: ; Bromine monoxide + Oxygen: Bromine (Br) combines with ozone forming bromine monoxide (BrO) and Oxygen (Oz). The BrO further reacts with chlorine monoxide (ClO) to give oxygen (Oz) and free atoms of brornine (Br) and chlorine (Cl).ā€
Why relevant

Mentions several bromine‑containing compounds (halons, hydrobromo fluorocarbons) used in fire‑related applications, linking bromine chemistry to fire‑suppression/retardant uses.

How to extend

A student could combine this with the POPs/bioaccumulation rules to consider that brominated chemicals used for fire protection might share behaviour (persistence/accumulation) with other brominated compounds.

Pattern takeaway: UPSC consistently targets 'Halogenated Hydrocarbons'. Whether it's DDT (Chlorine), CFCs (Chlorine/Fluorine), or BFRs (Bromine), the testing pattern is identical: they are stable, resist degradation, and accumulate in fatty tissues. If you see a 'Why is X chemical bad?' question, look for these traits.
How you should have studied
  1. [THE VERDICT]: Concept-based Current Affairs. Solvable via the 'POPs Framework' found in Shankar IAS (Chapter 28) or NCERT Biology (Class 12, Ecology).
  2. [THE CONCEPTUAL TRIGGER]: The Stockholm Convention on Persistent Organic Pollutants. Whenever a new chemical is added (like BFRs were around this time), its properties become high-yield.
  3. [THE HORIZONTAL EXPANSION]: Memorize the 'Dirty Dozen' POPs (e.g., DDT, PCBs, Dioxins) and the 'Nasty Newcomers' (PFAS, Endosulfan, Diclofenac). Understand the difference: Bioaccumulation (one organism over time) vs. Biomagnification (up the food chain).
  4. [THE STRATEGIC METACOGNITION]: Do not memorize individual chemical datasheets. Apply the 'Halogen Heuristic': If a man-made organic compound contains Chlorine, Bromine, or Fluorine (Halogens), assume it is lipophilic (fat-loving), persistent, and bioaccumulative until proven otherwise.
Concept hooks from this question
šŸ“Œ Adjacent topic to master
S1
šŸ‘‰ Persistence vs biodegradability of pollutants
šŸ’” The insight

The statement asks about resistance to degradation; multiple references discuss how pollutants vary in persistence and whether they are biodegradable or non-biodegradable.

High-yield for UPSC environment questions: understanding persistence underpins topics like pollutant fate, long-range transport, and remediation. It connects to waste management, ecology, and policy questions. Prepare by comparing examples of persistent vs biodegradable pollutants, mechanisms of breakdown (photolysis, microbial degradation), and implications for ecosystem health and cleanup.

šŸ“š Reading List :
  • Environment and Ecology, Majid Hussain (Access publishing 3rd ed.) > Chapter 6: Environmental Degradation and Management > Duration of Marine Pollutants > p. 46
  • Environment and Ecology, Majid Hussain (Access publishing 3rd ed.) > Chapter 6: Environmental Degradation and Management > Pollutant > p. 33
  • Science , class X (NCERT 2025 ed.) > Chapter 13: Our Environment > Activity 13.5 > p. 214
šŸ”— Anchor: "Are brominated flame retardants highly resistant to degradation and therefore pe..."
šŸ“Œ Adjacent topic to master
S1
šŸ‘‰ Persistent Organic Pollutants (POPs) — properties and impacts
šŸ’” The insight

POPs are defined as organic substances that remain intact for long periods, distribute widely, bioaccumulate and are toxic — directly relevant to claims of chemical persistence.

Frequently tested concept: POPs feature in questions on international conventions, human health, and bioaccumulation. Understanding the defining properties helps evaluate whether a chemical class (e.g., some flame retardants) could be treated as POPs. Study the POPs criteria, examples, and policy responses (e.g., Stockholm Convention).

šŸ“š Reading List :
  • Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 28: International Organisation and Conventions > POPs > p. 405
  • Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 5: Environmental Pollution > 5.r.r. Classifications > p. 63
šŸ”— Anchor: "Are brominated flame retardants highly resistant to degradation and therefore pe..."
šŸ“Œ Adjacent topic to master
S1
šŸ‘‰ Additives in plastics — flame retardants and remediation limits
šŸ’” The insight

References note presence of flame retardants as plastic additives and that bioremediation is limited to biodegradable compounds, highlighting potential remediation challenges for such additives.

Useful for questions on plastic pollution, product composition, and remediation policy. Shows how chemical additives complicate waste management and why persistence of additives matters. Prepare by linking material composition to disposal impacts and remediation feasibility.

šŸ“š Reading List :
  • Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 5: Environmental Pollution > 5.12.2. Plastics as a Waste Material in Land Environment > p. 97
  • Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 5: Environmental Pollution > Disadvantages of bioremediation > p. 101
šŸ”— Anchor: "Are brominated flame retardants highly resistant to degradation and therefore pe..."
šŸ“Œ Adjacent topic to master
S2
šŸ‘‰ Persistent Organic Pollutants (POPs) and bioaccumulation
šŸ’” The insight

Reference [1] defines POPs as organic chemicals that persist, distribute widely and accumulate in fatty tissue of living organisms via bioaccumulation.

High-yield environment topic: explains why certain synthetic organics pose long-term risks to human and wildlife health. Mastering this helps answer questions on pollutant persistence, health impacts, and policy responses. Study by linking POP properties (persistence, lipophilicity, long-range transport) to examples and health effects.

šŸ“š Reading List :
  • Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 28: International Organisation and Conventions > POPs > p. 405
šŸ”— Anchor: "Do brominated flame retardants bioaccumulate (accumulate) in humans and animals?"
šŸ“Œ Adjacent topic to master
S2
šŸ‘‰ Biological magnification (trophic accumulation)
šŸ’” The insight

Reference [2] describes progressive accumulation of non-degradable chemicals at each trophic level, leading to highest concentrations in top predators including humans.

Core ecology concept often tested in UPSC: connects food chains, human exposure to pollutants, and policy on pesticide residues. Learn typical pathways, implications for food safety, and example chemicals to answer multi-disciplinary questions.

šŸ“š Reading List :
  • Science , class X (NCERT 2025 ed.) > Chapter 13: Our Environment > 13.1.1 Food Chains and Webs > p. 212
šŸ”— Anchor: "Do brominated flame retardants bioaccumulate (accumulate) in humans and animals?"
šŸ“Œ Adjacent topic to master
S2
šŸ‘‰ Additives in plastics (including flame retardants) and environmental persistence
šŸ’” The insight

Reference [3] notes plastics contain additives such as flame retardants, plasticizers and pigments that can be persistent environmental contaminants.

Useful for questions on pollution sources, e-waste and chemical hazards; links manufacturing/materials to environmental and health outcomes. Prepare by mapping common additives, their uses, and environmental/health concerns as case studies.

šŸ“š Reading List :
  • Environment, Shankar IAS Acedemy .(ed 10th) > Chapter 5: Environmental Pollution > 5.12.2. Plastics as a Waste Material in Land Environment > p. 97
šŸ”— Anchor: "Do brominated flame retardants bioaccumulate (accumulate) in humans and animals?"
šŸŒ‘ The Hidden Trap

PFAS (Per- and polyfluoroalkyl substances). Known as 'Forever Chemicals', they are the modern sibling to BFRs. Found in non-stick cookware and water-resistant fabrics. Expect a question on their 'mobility' in water vs. BFRs' tendency to stick to soil/fat.

⚔ Elimination Cheat Code

The 'Definition of Concern' Logic. The question asks why there is 'concern'. In environmental science, 'concern' is defined by persistence and accumulation. If Statement 1 were false (i.e., it degrades easily), there would be no concern. Therefore, for the premise of the question to hold, the statements describing persistence usually must be true.

šŸ”— Mains Connection

Link to GS3 Environment (E-Waste Management Rules). BFRs are a primary reason why recycling E-waste is hazardous. Burning plastic wires releases Dioxins/Furans (Mains 2023 theme).

āœ“ Thank you! We'll review this.

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Why is there a great concern about the 'microbeads' that are released into environment?

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Consider the following pairs : Commonly used / consumed materials Unwanted or controversial chemicals likely to be found in them 1. Lipstick - Lead 2. Soft drinks - Brominated vegetable oils 3. Chinese fast food - Monosodium glutamate Which of the pairs given above is/are correctly matched ?