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Explanation: The way to approach this question is by understanding the oxidation number associated with each element in the compounds mentioned.
In the given answer, A-3 matches oxidation number 2 with Calcium in CaO2 which is correct since Calcium typically has an oxidation number of +2. B-4 Matches oxidation number 3 with Aluminum in NaAlH4. In this compound, Aluminum indeed has an oxidation number of +3. C-1 matches oxidation number 4 with Manganese in MnO2, which is correct as Manganese has +4 oxidation state in this compound. Lastly, D-2 matches oxidation number 6 with Sulfur in H2S2O7 where Sulfur has +6 oxidation state.
So the correct matching is A-3 (2 with Calcium), B-4 (3 with Aluminum), C-1 (4 with Manganese), D-2 (6 with Sulfur) and therefore, option 1 is the correct answer.